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Quantum Monte Carlo: hydrogen atom

The radial Schroedinger equation for the hydrogen atom can be written as

-\frac{\hbar^2}{2m}\frac{\partial^2 u(r)}{\partial r^2}- \left(\frac{ke^2}{r}-\frac{\hbar^2l(l+1)}{2mr^2}\right)u(r)=Eu(r),

or with dimensionless variables

-\frac{1}{2}\frac{\partial^2 u(\rho)}{\partial \rho^2}- \frac{u(\rho)}{\rho}+\frac{l(l+1)}{2\rho^2}u(\rho)-\lambda u(\rho)=0, \tag{3}

with the hamiltonian

H=-\frac{1}{2}\frac{\partial^2 }{\partial \rho^2}- \frac{1}{\rho}+\frac{l(l+1)}{2\rho^2}.