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Quantum Monte Carlo: the helium atom

This results in 1RT(r1)dRT(r1)dr1=Z, and RT(r1)eZr1. A similar condition applies to electron 2 as well. For orbital momenta l>0 we have 1RT(r)dRT(r)dr=Zl+1. Similarly, studying the case r120 we can write a possible trial wave function as ψT(R)=eα(r1+r2)eβr12. The last equation can be generalized to ψT(R)=ϕ(r1)ϕ(r2)ϕ(rN)i<jf(rij), for a system with N electrons or particles.