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More on Detailed Balance

The Metropolis choice is to maximize the A values, that is

\begin{equation} A_{j \rightarrow i} = \min \left ( 1, \frac{p_iT_{i\rightarrow j}}{ p_jT_{j\rightarrow i}}\right ). \tag{9} \end{equation}

Other choices are possible, but they all correspond to multilplying A_{i\rightarrow j} and A_{j\rightarrow i} by the same constant smaller than unity. The penalty function method uses just such a factor to compensate for p_i that are evaluated stochastically and are therefore noisy.

Having chosen the acceptance probabilities, we have guaranteed that if the {\cal w}_i^{(n)} has equilibrated, that is if it is equal to p_i , it will remain equilibrated. Next we need to find the circumstances for convergence to equilibrium.