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Matrix elements of Slater determinants

The efficiency can be improved however if we move only one electron at the time. The Slater determinant matrix \hat{D} is defined by the matrix elements

d_{ij}=\phi_j(x_i)

where \phi_j(\mathbf{r}_i) is a single particle wave function. The columns correspond to the position of a given particle while the rows stand for the various quantum numbers.