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The Metropolis Algorithm and Detailed Balance

We obtain then (using the Boltzmann distribution) \begin{equation*} \frac{A(j\rightarrow i)}{A(i\rightarrow j)}= \exp{(-\beta(E_i-E_j))} . \end{equation*} We are in this case interested in a new state E_j whose energy is lower than E_i , viz., \Delta E = E_j-E_i \le 0 . A simple test would then be to accept only those microstates which lower the energy. Suppose we have ten microstates with energy E_0 \le E_1 \le E_2 \le E_3 \le \dots \le E_9 . Our desired energy is E_0 .