The compiler must see a declaration of a function before you can call it (the compiler checks the argument and return types). The declaration of library functions appears in so-called "header files" that must be included in the program, e.g.,
#include <stdlib.h> /* atof function */
We call three functions (atof, sin, printf) and these are declared in three different header files. The main program is a function called main with a return value set to an integer, int (0 if success). The operating system stores the return value, and other programs/utilities can check whether the execution was successful or not. The command-line arguments are transferred to the main function through
int main (int argc, char* argv[])