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Time Auto-correlation Function

If we assume that \lambda_0 is the largest eigenvector we see that in the limit t\rightarrow \infty , \mathbf{\hat{w}}(t) becomes proportional to the corresponding eigenvector \mathbf{\hat{v}}_0 . This is our steady state or final distribution.

We can relate this property to an observable like the mean energy. With the probabilty \mathbf{\hat{w}}(t) (which in our case is the squared trial wave function) we can write the expectation values as

\langle \mathbf{M}(t) \rangle = \sum_{\mu} \mathbf{\hat{w}}(t)_{\mu}\mathbf{M}_{\mu},

or as the scalar of a vector product

\langle \mathbf{M}(t) \rangle = \mathbf{\hat{w}}(t)\mathbf{m},

with \mathbf{m} being the vector whose elements are the values of \mathbf{M}_{\mu} in its various microstates \mu .