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Time Auto-correlation Function

If we assume that λ0 is the largest eigenvector we see that in the limit t, ˆw(t) becomes proportional to the corresponding eigenvector ˆv0. This is our steady state or final distribution.

We can relate this property to an observable like the mean energy. With the probabilty ˆw(t) (which in our case is the squared trial wave function) we can write the expectation values as

M(t)=μˆw(t)μMμ,

or as the scalar of a vector product

M(t)=ˆw(t)m,

with m being the vector whose elements are the values of Mμ in its various microstates μ.